In Situ Bioremediation Using Molasses Injection at an Abandoned Manufacturing Facility, Emeryville, California

Site Name:

Abandoned Manufacturing Facility

Location:

Emeryville, California

Period of
Operation:

- Pilot study--August 1995 to February 1996
- Full scale system--ongoing,
data available from April 1997 to October 1998

Cleanup
Type:

Pilot and Full scale

Remediation
Contractor:

Daniel L. Jacobs
ARCADIS Geraghty & Miller, Inc.
3000 Cabot Boulevard West, Suite 3004
Langhorne, PA 19047
Telephone: (215) 752-6840
Fax: (215) 752-6879
E-mail: Djacobs@gmgw.com

Technology:
In situ bioremediation
- A pilot study was performed using a mixture of molasses, biologically inoculated solution (supernatant), and tap water was injected into the subsurface
- The full-scale system used 91 temporary injection points, installed to 24 ft bgs with a Geoprobe
- Molasses injection events were performed in April 1997 and February 1998, which involved a mixture of water, molasses, and a small amount of supernatant
- During the first injection event, each injection point received 25 gallons of molasses, 1 gallon of supernatant, and 125 gallons of water

Cleanup Authority:
State voluntary cleanup program

Site Contact:
Not identified
EPA Remedial Project Manager:
Eugene Dennis
U.S. EPA Region 3
1650 Arch Street (3HS21)
Philadelphia, PA 19103-2029
(215) 814- 3202
E-mail: dennis.eugene@epa.gov

Contaminants:
TCE, hexavalent chromium
- Concentrations of TCE reported as high as 12,000 æg/L

Waste Source:
Electroplating operations

Type/Quantity of Media Treated:
Groundwater
- Site geology consists of interbedded sand and clay units
- Depth to groundwater is approximately 3.5 to 8 ft
- Groundwater velocity is estimated at approximately 60 ft per yr

Purpose/Significance of Application:
Bioremediation of a site contaminated with both chlorinated solvents and hexavalent chromium

Regulatory Requirements/Cleanup Goals:
- The pilot study was performed to determine if TCE degradation and metal precipitation could be enhanced by an in situ reactive zone - Cleanup goals for the full-scale application were not identified

Results:
- The average TCE concentration in on-site wells has decreased by 99% (3,040 æg/L in April 1995 to 4 æg/L in October 1998) during bioremediation
- The trends for TCE degradation products (cis-1,2-DCE and VC) indicate that TCE has been reductively dechlorinated to ethene under the engineered anaerobic conditions; initial cis-1,2-DCE and VC concentrations increased following the first reagent injection, but declined as shown in the October 1998 groundwater monitoring results
- The average concentrations of total chromium and hexavalent chromium in the injection area have been reduced by approximately 98% and 99%, respectively

Cost Factors:
- The overall project cost was approximately $400,000
- No further information was provided about the components of this cost, such as a breakdown of capital or operations and maintenance (O&M) costs

Description:
Metal plating operations were conducted at a manufacturing facility located in Emeryville, California (actual site name confidential) from 1952 until 1989. Investigations conducted at the site found groundwater to be contaminated with chlorinated solvents, primarily TCE, and hexavalent chromium. From August 1995 to February 1996, the site owner conducted a pilot study of anaerobic reductive dechlorination to evaluate its potential as a groundwater remedy under a state voluntary cleanup program. Based on the results of the pilot test, a full-scale system was installed and is operating at the site.

The injection of molasses reagent solution created conditions favorable for the reduction in TCE, DCE, VC, and chromium concentrations in the subsurface. During an 18-month period of full-scale operation, average concentrations of TCE were reduced by 99%, from more than 3,000 ug/L to 4 ug/L, and average concentrations of Cr+6 also were reduced by 99%. The pilot study showed that the rate of reductive dechlorination could be enhanced with the use of an injected molasses solution.

The use of molasses injection was shown to create an anaerobic reactive zone in an 18-month period where concentrations of TCE, DCE, and hexavalent chromium were reduced. According to the PRP contractor, this technology was shown to save substantial resources when compared to pump and treat.