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5 EXTRACTION METHODS

5.6 SUPERCRITICAL FLUID EXTRACTION


Use: Extraction of chemical contaminants from water and soil samples.

Description:

Supercritical fluid extraction utilizes the increased solvency of supercritical fluids to extract contaminants from a sample. The supercritical fluid is mixed with the sample in an extractor vessel and the contaminants are dissolved and extracted to an equilibrium solubility level (typically about 10%). The gaseous solution then exits the extractor vessel and is passed through a pressure reduction valve, where the pressure (and the dissolving power) of the fluid is reduced, causing the contaminants to precipitate in a separation vessel. The fluid, under reduced pressure, flashes to a gaseous phase, leaving the contaminants in a liquid phase in the separation vessel. The contaminants are then recovered and analyzed. The solvent gas is recycled by a compressor, which raises the pressure of the gas until it condenses into a liquid and the process is repeated.

Analytes:

2. Non-Halogenated SVOCs 5. PAHs
4. Halogenated SVOCs 10. Explosives

Media:

Soil: Ground Water: Surface Water: Gas/Air:
MINIMUM MODERATE MODERATE Not Applicable
Maximum Depth: Not Applicable.
Production Rate: Sample is available quickly.
Investigation Derived Waste Volume: Medium volume of waste.
Technology Status: Commercially available technology with limited field experience.
Certification/Verification: Technology has not participated in CalEPA certification and/or CSCT verification program.
Relative Cost per Sample: Most expensive.

Limitations:

EPA Methods:

3560 Supercritical Fluid Extraction of Total Recoverable Petroleum Hydrocarbons.
3561 Supercritical Fluid Extraction of Polynuclear Aromatic Hydrocarbons.

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