| Use: | Extraction of chemical contaminants from water and soil samples. | 
Description:
Supercritical fluid extraction utilizes the increased solvency of supercritical fluids to extract contaminants from a sample. The supercritical fluid is mixed with the sample in an extractor vessel and the contaminants are dissolved and extracted to an equilibrium solubility level (typically about 10%). The gaseous solution then exits the extractor vessel and is passed through a pressure reduction valve, where the pressure (and the dissolving power) of the fluid is reduced, causing the contaminants to precipitate in a separation vessel. The fluid, under reduced pressure, flashes to a gaseous phase, leaving the contaminants in a liquid phase in the separation vessel. The contaminants are then recovered and analyzed. The solvent gas is recycled by a compressor, which raises the pressure of the gas until it condenses into a liquid and the process is repeated.
Analytes:
| 2. Non-Halogenated SVOCs | 5. PAHs | 
| 4. Halogenated SVOCs | 10. Explosives | 
Media:
| Soil: | Ground Water: | Surface Water: | Gas/Air: | 
| MINIMUM | MODERATE | MODERATE | Not Applicable | 
| Maximum Depth: | Not Applicable. | 
| Production Rate: | Sample is available quickly. | 
| Investigation Derived Waste Volume: | Medium volume of waste. | 
| Technology Status: | Commercially available technology with limited field experience. | 
| Certification/Verification: | Technology has not participated in CalEPA certification and/or CSCT verification program. | 
| Relative Cost per Sample: | Most expensive. | 
Limitations:
EPA Methods:
| 3560 | Supercritical Fluid Extraction of Total Recoverable Petroleum Hydrocarbons. | 
| 3561 | Supercritical Fluid Extraction of Polynuclear Aromatic Hydrocarbons. | 
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