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7 SAMPLE ANALYSIS TOOLS for METALS

7.1 EX-SITU ANALYSIS

7.1.9 Amperometric and Galvanic Cell Sensor


Use: Ambient air quality monitoring of metals.

See 6.2.21 for use with VOCs, SVOCs, and pesticides.

Description:

Amperometric and galvanic sensors measure an electrochemical response when the sensor comes into contact with the analyte of interest Each probe contains a sensor which is specifically sensitive to a particular gas or vapor. An internal pump draws an air sample into the analyzer. These sensors typically consist of electrodes in contact with an electrolyte-saturated insulator. Selective membranes allow the gas of interest to enter the insulator, and redox reaction on the sensing-electrode surface generates a current that is proportional to the analyte concentration. When an analyte is present, it will absorb to the thin-film sensor which undergoes a change in electrical resistance proportional to the mass of analyte absorbed onto its surface. This change is measured and converted to a vapor concentration that is displayed on the readout of the analyzer.

Analytes:

7. Metals

Media:

Soil/Sediment Water Gas/Air
Requires extraction to gas phase Requires extraction to gas phase BETTER
Selectivity: Technique measures the contaminant directly.
Susceptibility to Interference: Medium.
Detection Limits : 10-100 ppm (soil); 0.5-10 ppm (water).
Turnaround Time per Sample: Minutes.
Applicable To:
Screen/Identify Characterize Concentration/Extent Cleanup Performance Long-Term Monitoring
BETTER ADEQUATE BETTER BETTER
Quantitative Data Capability: Data become quantitative with additional effort.
Technology Status: Commercially available technology with moderate field experience.
Certification/Verification: Technology has not participated in CalEPA certification and/or CSCT verification program.
Relative Cost per Analysis: Least expensive.

Limitations:

ASTM Standards/EPA Methods:

No applicable ASTM standards or EPA methods are cited for this technology.


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