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8 SAMPLE ANALYSIS TOOLS for RADIONUCLIDES

8.2 EX-SITU ANALYSIS

8.2.3 Nuclear Magnetic Resonance


Use: Invaluable tool for determining the molecular structure of both large and small molecules and is increasingly used to create three-dimensional images of density or composition distribution in homogeneous materials. Primarily used as a research tool.

Description:

Nuclear magnetic resonance (NMR) spectroscopy is the absorption of radio frequency (RF) radiation by a nucleus in a strong magnetic field. Absorption of the radiation causes the nuclear spin to realign or flip in the higher-energy direction. After absorbing energy the nuclei will re-emit RF radiation and return to the lower-energy state. The energy of an NMR transition depends on the magnetic field strength and a proportionality factor for each nucleus called the magnetogyric ratio. The local environment around a given nucleus in a molecule will slightly perturb the local magnetic field exerted on that nucleus and affect its exact transition energy. This dependence of the transition energy on the position of a particular atom in a molecule makes NMR spectroscopy extremely useful for determining the structure of molecules.

Analytes:

8. Radionuclides

Media:

Soil/Sediment Water Gas/Air
BETTER BETTER BETTER
Selectivity: Technique measures the contaminant directly.
Susceptibility to Interference: Medium.
Detection Limits : 500+ ppm (soil); 100+ ppm (water).
Turnaround Time per Sample: Minutes.
Applicable To:
Screen/Identify Characterize Concentration/Extent Cleanup Performance Long-Term Monitoring
BETTER BETTER BETTER BETTER
Quantitative Data Capability: Data become quantitative with additional effort.
Technology Status: Commercially available technology with limited field experience.
Certification/Verification: Technology has not participated in CalEPA certification and/or CSCT verification program.
Relative Cost per Analysis: Mid-range expense.

Limitations:

ASTM Standards/EPA Methods:

No applicable ASTM standards or EPA methods are cited for this technology.


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