17-2 Hazard Analysis
Principal unique hazards associated with ultraviolet oxidation
include:
a. Physical Hazards
(1) Description: Certain components of UV treatment systems, such as
the UV lamps and the ozone generator, may generate heated surfaces which may cause burns
to unprotected skin.
Control: These heated surfaces may be insulated or cooled either by
ventilation or through a heat exchanger. Insulated gloves may be worn to prevent heat
thermal burns. CONTROL POINT: Design, Operations, Maintenance
(2) Description: UV oxidation systems utilize high-voltage mercury
lamps which may operate on voltages up to 3,000 volts. Breakage of the lamps may cause
electrocution.
Control: Verify that the hazardous area classifications, as defined
in NFPA 70-500-1 through 500-10, are indicated on the drawings. All controls, wiring, and
equipment should be in conformance with the requirements of EM 385-1-1, Section 11.G or
NFPA 70 for the identified hazard areas. High-voltage components should be provided with
ground-fault protection if required by EM 385 1-1, Section 11 or NFPA 70 requirements.
Cover panels of the UV lamps should be equipped with interlocks that ensure the system is
de-energized when doors are opened. CONTROL POINT: Design, Construction, Operations,
Maintenance
(3) Description: Although hydrogen peroxide solutions (27-52%) are
not combustible, as strong oxidizers they can greatly intensify combustion. They also
present an explosion hazard because of violent decomposition when heated or contaminated
with oxidizable materials including iron, copper, brass, bronze, copper, and other metals
(see Material Safety Data Sheets for complete listing). Contact with reducing agents, or
organic and combustible materials (wood, paper) may cause immediate spontaneous ignition.
Control: A plant-specific lock-out/tag-out program designed after
the requirements of 29 CFR 1910.147 should be implemented for maintenance procedures.
Plant operators should become familiar with the reactive properties of hydrogen peroxide
through a plant-specific hazard communication program designed in compliance with the
requirements of 29 CFR 1910.1200. Store hydrogen peroxide solutions in their original
containers in a cool, clean, fire-resistant area away from combustible materials,
catalytic metals, direct sunlight, and other potential sources of heat and/or ignition.
Maintaining the purity of the solution is important. Do not return unused material to its
storage container after removal. All equipment that may contact hydrogen peroxide
solutions should be selected, designed, and maintained to minimize the reactive hazards of
these materials. It is recommended that the storage location have secondary containment.
An ample source of water must be readily available for handling spills. CONTROL POINT:
Design, Operations, Maintenance
(4) Description: UV oxidation facilities may contain vaults and
vessels which require entry as a normal part of operation and maintenance. These spaces
have the potential to contain hazardous atmospheres, and/or engulfment dangers due to the
nature of materials and equipment used in the treatment process.
Control: Designers should, where possible, eliminate confined space
in the design. If confined spaces can not be eliminated, designers should seek to minimize
maintenance requirements in these spaces. Despite efforts to reduce the number of confined
spaces which require entry, treatment plants will, out of operational necessity, have
confined spaces. Dangers posed by confined space which require entry are best controlled
by plant personnel following a plant-specific confined-space entry program designed after
the requirements specified in the Occupational Safety and Health Administration=s (OSHA's)
confined-space standard in 29 CFR 1910.146. Designers should ensure that liquid oxygen
storage vessels and distribution systems comply with the requirements specified in NFPA 50
and 29 CFR 1910.104. Plant operators should become familiar with the hazardous properties
of liquid oxygen through a plant-specific hazard communication program designed in
compliance with the requirements of 29 CFR 1910.1200. CONTROL POINT: Design, Operations,
Maintenance
(5) Description: Operation of UV oxidation systems can generate
gases and build pressure in the process units. There is a hazard for the workers for an
explosion and release of the reagents and contaminated materials. Some UV/oxidation
systems use liquid oxygen to generate ozone. Liquid oxygen storage creates the potential
for fire and explosion.
Control: Designers should include pressure-relief valves and vents
discharged away from the work area. Alarm systems and monitors to detect pressure
build-up, emergency release systems for head spaces, and emergency plans for operations
should also be considered. CONTROL POINT: Design, Operations, Maintenance
(6) Description: Permanent or semi-permanent treatment buildings may
present life safety hazards such as inadequate egress, fire suppression systems, and/or
emergency lighting systems.
Control: Permanent and semi-permanent treatment system buildings
should be constructed in accordance with ANSI 58.1: Minimum Design Loads for Buildings and
Other Structures; the National Fire Code; the National Standard Plumbing Code; Life Safety
Code; and the Uniform Building Code. Depending on where the project is located, the
structures must also comply with the Air Force Manuals on Air Force bases, the USACE
Technical Manuals on Army installations, or Local Building Codes on Superfund, BRAC, or
FUDS project sites. CONTROL POINT: Design, Operations
(7) Description: The operation of a UV-based treatment system
utilizes lamps that emit UV radiation that may cause eye damage.
Control: Workers should minimize their exposure to the UV light by
wearing the appropriate ANSI-approved eye protection, utilizing the appropriate shade.
CONTROL POINT: Operations, Maintenance
(8) Description: Noise hazards may be associated with the use of an
air compressor to generate ozone.
Control: Isolated generator rooms should be included in the design
and a hearing protection policy should be developed in accordance with 29 CFR 1910.95.
CONTROL POINT: Design, Operations, Maintenance
(9) Description: Emergency shower/eye wash equipment required per 19
CFR 1910.151 is not always provided with adequate floor drains, thereby creating potential
electrical hazards or walking surface hazards during required testing/use.
Control: Showers/eye wash equipment should be equipped with
accompanying functional drains to isolate and collect the shower/eye wash water from
unprotected electrical equipment and walking surfaces that, when wet, create slipping
hazards. CONTROL POINT: Design
b. Chemical Hazards
(1) Description: Workers may be exposed to mercury if
mercury-vapor-filled lamps are damaged or broken during installation, inspection, or
replacement. Mercury overexposure may cause various symptoms including damage to the
central nervous system, conjunctivitis, and inflammation to the nose and throat.
Control: Mercury lamps should be handled with caution to help
prevent breakage, and mercury spills should be immediately removed. Mercury spill kits
should be available in the immediate work areas. CONTROL POINT: Construction,
Operations, Maintenance
(2) Description: Ozone may be produced via an on-site ozonator to
enhance the performance of UV oxidation systems. Ozone may leak through seals or pipe
junctions, or ozone levels may increase in the work environment if the ozonator fouls.
Ozone is a potential experimental tumorigen and teratogen. Exposure to ozone may irritate
exposed skin. Depending upon the degree of exposure, ozone may cause irritation of the
eyes and respiratory tract, diminished lung function, pain or difficulty breathing, chest
tightness, coughing, wheezing, increased sensitivity of the lungs to allergens and
bronchoconstrictors, and increased susceptibility to lung-based bacterial and viral
infections.
Control: Ozone may be removed by local or general ventilation of the
work area. The UV chambers should have closed tops and controlled vents. Gas-tight covers
may be required on sumps and holding tanks downstream of ozone generation systems. The
vessels should be passively ventilated or actively ventilated through ozone decomposition
equipment to the outside of the building. Equipment should be interlocked with ozone
generation equipment and set to shut ozone generation off if plant levels exceed the ACGIH
TLV for ozone. Monitors should set off alarms to warn treatment plant operators if plant
levels exceed the ACGIH STEL. A plant-specific hazard communication program should address
the symptoms of ozone exposure and procedures to reduce exposures to acceptable levels.
CONTROL POINT: Design, Operations, Maintenance
(3) Description: Worker inhalation/ingestion/dermal exposure may
occur during the use of catalysts (compounds which lower energy required for a chemical
reaction to occur) that may be used in the treatment of waste materials in conjunction
with UV oxidation. In addition, workers may be exposed to acids and bases which may be
used in the process to control pH levels.
Control: Catalysts used in this treatment process may act as
sensitizers, and all contact should be minimized. Workers should wear personal protective
equipment and clothing (e.g. an air-purifying respirator with HEPA(N100, R100, P100)
filters, chemically-resistant disposable coveralls, and protective gloves (e.g. nitrile)),
as appropriate, based on the materials to be handled. CONTROL POINT: Design, Operations,
Maintenance
(4) Description: Hydrogen peroxide may also be used to help improve
the efficiency of UV oxidation systems. Hydrogen peroxide is an oxidizer that may react
violently with organic materials either in the waste stream or in other materials, causing
fire or system over-pressurization. Exposure to hydrogen peroxide may cause irritation or
chemical burns to the skin and damage eyes. Dermal or eye contact with, or
inhalation of, the splatters or mists of hydrogen peroxide solutions pose a hazard to
personnel due to chemical burns associated with acute exposure.
Control: Secondary containment is required for storage of hydrogen
peroxide. Whenever possible, hydrogen peroxide solutions should be automatically fed into
the treatment system. If manual addition of the solutions is required, protective clothing
will be necessary. Gloves made of natural rubber or nitrile offer good chemical resistance
to solutions of 30-70% hydrogen peroxide. Leather and many fabrics, including cotton,
rayon, and wool, should not be worn when handling hydrogen peroxide solutions because they
present a fire hazard if they become contaminated with hydrogen peroxide. It is
recommended that garments of polyester-acrylic (anti-static treated) fiber be worn when
handling hydrogen peroxide solutions. Splash-proof chemical safety goggles and
face-shields should also be worn. Control mists with local ventilation or by
respiratory protection, as determined by a qualified health and safety professional.
CONTROL POINT: Design, Operations, Maintenance
(5) Description: Workers may be exposed to pH control agents (acids
and bases) during operations.
Control: The secondary containment storage areas for acids and bases
should be constructed of materials compatible with storage of these materials and clearly
marked. Acids and bases should be stored in separate areas. Emergency showers and eye wash
stations that comply with 29 CFR 1910.151(c), and the design requirements specified in
ANSI Z358,1 (1990), should be located near the reagent storage areas. Handling of pH
agents should be automated to the extent practical. An emergency plan should be prepared
and facility personnel should be trained to safely handle acids and bases. Manual
handling of acids and bases should be done by personnel familiar with their properties and
equipped with personal protective equipment (PPE), such as leather or rubber
acid-resistant boots, chemical-resistant coveralls, goggles and face shields,
air-purifying respirators (as indicated by the reagent), and rubber or other acid and base
resistant gloves (e.g. nitrile) or gauntlets. CONTROL POINT: Design, Operations,
Maintenance
c. Radiological Hazards
Description: The mercury lamps used in the treatment generate high
levels of UV radiation. Typically the UV is contained within the treatment unit. However,
radiation that is released may damage eyes or increase the risk of skin cancer.
Control: To protect personnel from radiation exposure, the reactor
vessel must be equipped with interlocks that de-energize the system when the door is
opened. Viewing ports in reactor walls may be equipped with glass covers that prevent
transmission of UV radiation. CONTROL POINT: Design, Operation, Maintenance
d. Biological Hazards
Description: NONAPPLICABLE
Control: NONAPPLICABLE
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