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2.5.2 Common Treatment Technologies for Nonhalogenated SVOCs in Soil, Sediment, Bedrock and Sludge |
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Common treatment technologies for nonhalogenated SVOCs in soil, sediment, and sludge include biodegradation, incineration, and excavation with off-site disposal. All types of biodegradation, both in situ or ex situ, can be considered to remediate soils: in situ bioremediation, bioventing, composting, controlled solid phase, or landfarming. Slurry phase biological treatment is also applicable but is less widely used. Treatability studies should be conducted to evaluate design parameters, such as degradation rates, supplemental organism addition, cleanup levels achievable, degradation intermediates, and nutrient/oxygen addition. Biodegradation uses a process in which indigenous or inoculated microorganisms (e.g., fungi, bacteria, and other microbes) degrade (i.e., metabolize) organic contaminants found in soil and/or ground water. In the presence of sufficient oxygen (aerobic conditions), microorganisms will ultimately convert many organic contaminants to carbon dioxide, water, and microbial cell mass. In the absence of oxygen (anaerobic conditions), the contaminants will be ultimately metabolized to methane and carbon dioxide. Sometimes contaminants may not be completely degraded, but only transformed to intermediate products that may be less, equally, or more hazardous than the original contaminant. In situ bioremediation of soil typically involves the percolation or injection of ground water or uncontaminated water containing dissolved oxygen and nutrients. Ex situ bioremediation typically uses tilling or continuously mixed slurries to apply oxygen and nutrients, and is performed in a prepared bed (liners and aeration) or reactor. Bioventing is also potentially applicable to some nonhalogenated SVOCs. Incineration uses high temperatures, 870o to 1,200o C (1,400o to 2,200o F), to volatilize and combust (in the presence of oxygen) organic constituents in hazardous wastes. The destruction and removal efficiency (DRE) for properly operated incinerators exceeds the 99.99% requirement for hazardous waste. Distinct incinerator designs available for solids are rotary kiln, fluidized bed, and infrared units. All three types have been used successfully at full scale. Excavation, retrieval, and
off-site disposal of contaminated soil (with or
without stabilization) to a landfill have been performed
extensively at many sites. Landfilling of hazardous materials,
especially hazardous wastes, is becoming increasingly difficult
and expensive as a result of growing regulatory control, and may
be cost-prohibitive for sites with large volumes, greater depths,
or complex hydrogeologic environments. Determining the
feasibility of off-site disposal requires knowledge of land
disposal restrictions and other regulations developed by state
governments. |
Notice | |
Foreword | |
Report Documentation Page | |
Acknowledgement | |
Objectives | |
Background | |
How to use this document | |
Natural Resources | |
Cautionary Notes | |
Online Survey |
Presumptive Remedies | |
Data Requirements | |
Nonhalogenated VOCs | |
Halogenated VOCs | |
Nonhalogenated SVOCs | |
Halogenated SVOCs | |
Fuels | |
Inorganics | |
Radionuclides | |
Explosives |
Soil,Sed.,Bedrock & Sludge | |
In Situ Biological | |
In Situ Phys/Chem | |
In Situ Thermal | |
Ex Situ Biological | |
Ex Situ Phys/Chem | |
Ex Situ Thermal | |
Containment | |
Other Treatment | |
Ground,Surf. H2O,Leachate | |
In Situ Biological | |
In Situ Phys/Chem | |
Ex Situ Biological | |
Ex Situ Phys/Chem | |
Containment | |
Off Gas & Air Emissions | |
Biofiltration | |
High Energy Destruction | |
Membrane Separation | |
Oxidation | |
Scrubbers | |
Carbon Adsorption |
Document Sources | |
Listing by Author | |
Listing of Websites |
A. Vendors | |
B. Site Projects | |
C. Federal Databases | |
D. Factors Affecting Treat. | |
E. Source Documents | |
F. Synonyms |
Site Map | |
Screening Matrix | |
Synonym List | |
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Soil,Sed.,Bedrock & Sludge | |
Gr. & Surf. H2O, Leachate | |
Air Emissions/Off-Gases |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Techs for Air Emissions | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Techs for Air Emissions | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Techs for Air Emissions | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Biological Techs | |
Thermal Techs | |
Other Techs | |
Common Techs | |
Treatment Train |
Bioventing | |
Enhanced Bioremediation | |
Phytoremediation |
Chemical Oxidation | |
Electrokinetic Sep. | |
Fracturing | |
Soil Flushing | |
Soil Vapor Extraction | |
Solidification/Stabilization |
Thermal Treatment |
Biopiles | |
Composting | |
Landfarming | |
Slurry Phase |
Chemical Extraction | |
Chemical RedOx | |
Dehalogenation | |
Separation | |
Soil Washing | |
Solidification/Stabilization |
Hot Gas Decon. | |
Incineration | |
OB/OD | |
Pyrolysis | |
Thermal Desorption |
Landfill Cap | |
Landfill Cap Enhancements |
Off-Site Disposal |
Enhanced Biodegradation | |
Natural Attenuation | |
Phytoremediation |
Air Sparging | |
Bioslurping | |
Chemical Oxidation | |
Directional Wells | |
Dual Phase Extraction | |
Thermal Treatment | |
Hydrofracturing | |
Air Stripping | |
Treatment Walls |
Bioreactors | |
Constructed Wetlands |
Adsorption/Absorption | |
Adv. Oxidation Processes | |
Air Stripping | |
GAC | |
Ground Water Pumping | |
Ion Exchange | |
Prec./Coag./Flocc. | |
Separation | |
Sprinkler Irrigation |
Physical Barriers | |
Deep Well Injection |