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2.8.2 Common Treatment Technologies for Inorganics in Soil, Sediment, Bedrock and Sludge |
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The most commonly used treatment technologies for inorganics in soil, sediment, and sludge include solidification/stabilization (S/S), excavation and off-site disposal, and acid extraction. These treatment technologies are described briefly below. Solidification processes produce monolithic blocks of waste with high structural integrity. The contaminants do not necessarily interact chemically with the solidification reagents (typically cement/ash) but are mechanically locked within the solidified matrix. Stabilization methods usually involve the addition of chemical binders, such as cement, silicates, or pozzolans, which limit the solubility or mobility of waste constituents even though the physical handling characteristics of the waste may not be changed or improved. Methods involving S/S techniques are often proposed in RODs and RI/FSs for lead battery recycling sites. Solidification/stabilization of contaminated soil can be conducted either in situ or ex situ. In situ S/S techniques are now considered innovative and are discussed in Section 4. Excavation and off-site disposal of contaminated soil (with or without solidification/stabilization pretreatment) to a landfill have been performed extensively at many sites. Landfilling of hazardous materials, especially hazardous wastes, is becoming increasingly difficult and expensive as a result of growing regulatory control, and may be cost-prohibitive for sites with large volumes, greater depths, or complex hydrogeologic environments. In addition, disposal capacity for radioactive and mixed waste is extremely limited. Determining the feasibility of off-site disposal requires knowledge of land disposal restrictions and other regulations developed by state governments. Acid extraction uses an acid, such as hydrochloric acid, to extract heavy metal contaminants from soils. In this process, soils are first screened to remove coarse solids. Hydrochloric acid is then introduced into the soil in the extraction unit. The residence time in the unit varies depending on the soil type, contaminants, and contaminant concentrations, but generally ranges between 10 and 40 minutes. The soil-extractant mixture is continuously pumped out of the mixing tank, and the soil and extractant are separated using hydrocyclones. |
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Nonhalogenated VOCs | |
Halogenated VOCs | |
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Inorganics | |
Radionuclides | |
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Soil,Sed.,Bedrock & Sludge | |
In Situ Biological | |
In Situ Phys/Chem | |
In Situ Thermal | |
Ex Situ Biological | |
Ex Situ Phys/Chem | |
Ex Situ Thermal | |
Containment | |
Other Treatment | |
Ground,Surf. H2O,Leachate | |
In Situ Biological | |
In Situ Phys/Chem | |
Ex Situ Biological | |
Ex Situ Phys/Chem | |
Containment | |
Off Gas & Air Emissions | |
Biofiltration | |
High Energy Destruction | |
Membrane Separation | |
Oxidation | |
Scrubbers | |
Carbon Adsorption |
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Soil,Sed.,Bedrock & Sludge | |
Gr. & Surf. H2O, Leachate | |
Air Emissions/Off-Gases |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Techs for Air Emissions | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Techs for Air Emissions | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Techs for Air Emissions | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Techs for H2O | |
Treatment Train |
Properties & Behavior | |
Techs for Soil | |
Biological Techs | |
Thermal Techs | |
Other Techs | |
Common Techs | |
Treatment Train |
Bioventing | |
Enhanced Bioremediation | |
Phytoremediation |
Chemical Oxidation | |
Electrokinetic Sep. | |
Fracturing | |
Soil Flushing | |
Soil Vapor Extraction | |
Solidification/Stabilization |
Thermal Treatment |
Biopiles | |
Composting | |
Landfarming | |
Slurry Phase |
Chemical Extraction | |
Chemical RedOx | |
Dehalogenation | |
Separation | |
Soil Washing | |
Solidification/Stabilization |
Hot Gas Decon. | |
Incineration | |
OB/OD | |
Pyrolysis | |
Thermal Desorption |
Landfill Cap | |
Landfill Cap Enhancements |
Off-Site Disposal |
Enhanced Biodegradation | |
Natural Attenuation | |
Phytoremediation |
Air Sparging | |
Bioslurping | |
Chemical Oxidation | |
Directional Wells | |
Dual Phase Extraction | |
Thermal Treatment | |
Hydrofracturing | |
Air Stripping | |
Treatment Walls |
Bioreactors | |
Constructed Wetlands |
Adsorption/Absorption | |
Adv. Oxidation Processes | |
Air Stripping | |
GAC | |
Ground Water Pumping | |
Ion Exchange | |
Prec./Coag./Flocc. | |
Separation | |
Sprinkler Irrigation |
Physical Barriers | |
Deep Well Injection |